ArticleDecember 31, 2015
Abstract
A hydrogel with tunable potential functionalization sites has been successfully prepared. As potential functionalization sites, (2-hydroxypropyl)-α-CDs (Hy-α-CDs) were introduced into the network of tetrahedron-like poly(ethylene glycol) (tetra-PEG) gel through supramolecular chemistry. In the stage of complexation, poly-pseudo-rotaxane consisting of tetra-PEG macromonomer and Hy-α-CD formed in pregel solution. The dynamic complexation process and the structure of the poly-pseudo-rotaxane were investigated by NMR experiment. In the stage of gelation, some cross-linking reactions were completed through click chemistry. The structures and mechanical properties of the resultant hydrogels were characterized by ATR-FTIR, XPS, SEM, and compression test in detail. The number of Hy-α-CD introduced into the hydrogel is related closely to the structure of the poly-pseudo-rotaxane and can be controlled easily by tuning the feed ratio. Anthracene as an example of function was introduced into the hydrogel through Hy-α-CD to preliminarily demonstrate the validity of the potential functionalization site in the last, and the hydrogel also has the capacity for further diverse functionalization.
Related products
Abbreviation: Tetrahydroxyl-terminated PEG (THPEG)
For more product information, please contact us at:
US Tel: 1-844-782-5734
US Tel: 1-844-QUAL-PEG
CHN Tel: 400-918-9898
Email: sales@sinopeg.com
